WebMay 17, 2010 · In this SOMO activation strategy, single-electron oxidation of a transient chiral enamine intermediate was achieved on treatment of enamines with suitable metal … WebOct 3, 2008 · As a critical design element, we presumed that the use of a suitable chiral amine catalyst would induce high enantioselectivity. Moreover, we recognized that the …

EnantioselectiveLinchpinCatalysisbySOMOCatalysis:AnApproach to the …

WebMay 9, 2007 · Such SOMO-activation was previously known only in a single example of a light-driven enantioselective reaction 10 and in reactions that were not enantioselective and which required a whole ... WebAbstract. Singly occupied molecular orbital (SOMO) catalysis allows an enantioselective organocatalytic α-enolation of aldehydes. A chiral secondary amine catalyst reacts with … great jobs in hawaii

Organocatalytic SOMO reactions of copper(I)-acetylide and

WebDec 1, 2008 · Design Plan. In our previous SOMO catalysis studies, we exploited the capacity of the aldehyde-derived radical cation DFT-2 7 to rapidly engage electron-rich olefins that incorporate traceless activation handles (e.g., enolsilanes, allylsilanes, vinyl trifluoroborate salts). 2, 4, 5 A common mechanistic feature of these coupling reactions is the transient … WebIn chemistry, HOMO and LUMO are types of molecular orbitals.The acronyms stand for highest occupied molecular orbital and lowest unoccupied molecular orbital, … WebSignificance. The authors report a direct enantioselective allylic alkylation of aldehydes using SOMO activation. They recognized that a one-electron oxidation of a transient … floating pool noodle table